Handbook of Radical Polymerization (K. Matyjaszewski & T. P. Davis)(1).pdf

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HANDBOOK OF RADICAL
POLYMERIZATION
HANDBOOK OF RADICAL
POLYMERIZATION
Krzysztof Matyjaszewski
Carnegie Mellon University, Pittsburgh, Pennsylvania
Thomas P. Davis
University of New South Wales, Sydney, Australia
A John Wiley & Sons, Inc. Publication
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Cover image: AFM image of densely grafted polystyrene brushes prepared by ATRP. Reprinted from:
K. L. Beers, S. G. Gaynor, K. Matyjaszewski, S. S. Sheiko, and M. Moeller, Macromolecules,
31, 9413 (1998).
This book is printed on acid-free paper.
Copyright # 2002 By John Wiley and Sons, Inc., Hoboken. All rights reserved.
Published simultaneously in Canada.
No part of this publication may be reproduced, stored in a retrieval system or transmitted in any
form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise,
except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without
either the prior written permission of the Publisher, or authorization through payment of the
appropriate per-copy fee to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA
01923, (978) 750-8400, fax (978) 750-4744. Requests to the Publisher for permission should be
addressed to the Permissions Department, John Wiley & Sons, Inc., 605 Third Avenue, New York,
NY 10158-0012, (212) 850-6011, fax (212) 850-6008, E-mail: PERMREQ@WILEY.COM.
For ordering and customer service, call 1-800-CALL-WILEY.
Library of Congress Cataloging-in-Publication Data is available
0-471-39274-X
Printed in the United States of America.
10987654321
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CONTENTS
Introduction
vii
Krzysztof Matyjaszewski and Thomas P. Davis
Contributors
xi
1 Theory of Radical Reactions
1
Johan P. A. Heuts
2 Small Radical Chemistry
77
Martin Newcomb
3 General Chemistry of Radical Polymerization
117
Bunichiro Yamada and Per B. Zetterlund
4 The Kinetics of Free Radical Polymerization
187
Christopher Barner-Kowollik, Philipp Vana, and Thomas P. Davis
5 Copolymerization Kinetics
263
Michelle L. Coote and Thomas P. Davis
6 Heterogeneous Systems
301
Alex M. van Herk and Michael Monteiro
7 Industrial Applications and Processes
333
Michael Cunningham and Robin Hutchinson
8 General Concepts and History of Living
Radical Polymerization
361
Krzysztof Matyjaszewski
9 Kinetics of Living Radical Polymerization
407
Takeshi Fukuda, Atsushi Goto, and Yoshinobu Tsujii
10 Nitroxide Mediated Living Radical Polymerization
463
Craig J. Hawker
v
vi
CONTENTS
11 Fundamentals of Atom Transfer Radical Polymerization
523
Krzysztof Matyjaszewski and Jianhui Xia
12 Control of Free Radical Polymerization by Chain
Transfer Methods
629
John Chiefari and Ezio Rizzardo
13 Control of Stereochemistry of Polymers in
Radical Polymerization
691
Akikazu Matsumoto
14 Macromolecular Engineering by Controlled
Radical Polymerization
775
Yves Gnanou and Daniel Taton
15 Experimental Procedures and Techniques for
Radical Polymerization
845
Stefan A. F. Bon and David M. Haddleton
16 Future Outlook and Perspectives
895
Krzysztof Matyjaszewski and Thomas P. Davis
Index
901

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