The Nitro Group in Organic Synthesis 2001 By Noboru Ono.pdf

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THE NITRO GROUP IN
ORGANIC SYNTHESIS
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ORGANIC NITRO CHEMISTRY SERIES
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THE NITRO GROUP IN
ORGANIC SYNTHESIS
Noboru Ono
A JOHN WILEY & SONS, INC., PUBLICATION
New York Chichester Weinheim Brisbane Singapore Toronto
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CONTENTS
Series Foreword
ix
Preface
xi
Acknowledgments
xiii
Abbreviations
xv
1. Introduction
1
2. Preparation of Nitro Compounds
3
2.1 Nitration of Hydrocarbons / 3
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2.2 Synthesis of Nitro Compounds by Oxidation / 20
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3. The Nitro-Aldol (Henry) Reaction
30
-Nitro Alcohols / 31
3.2 Derivativesfrom
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-Nitro Alcohols / 38
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3.3 Stereoselective Henry Reactions and Applications to Organic Synthesis / 51
β
4. MichaelAddition
70
4.1 Addition to Nitroalkenes / 70
v
3.1 Preparationof
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